Stable chromium isotopes as indicators of reduction and immobilization of hexavalent chromium in groundwater
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Redox reactions and the influence of natural Mn oxides on Cr oxidation in a contaminated site in northern Italy: evidence from Cr stable-isotopes and EPR spectroscopy
Hexavalent chromium-contaminated groundwaters and sediments in northern Italy have been studied using the Cr stable-isotope systematics and electron spin resonance spectroscopy (ESR), in order to explore redox changes and soil-groundwater interactions. The isotopic data indicate a possible Cr(VI) source released into the environment from an industrial plant. EPR spectra on the sediments which c...
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Abstract Introduction: Chromium is an extremely important heavy metal which is used in different industries. It can be found in water resources due to insufficient treatment of industrial wastewater. The goal of this study was to survey the feasibility of application of hexavalent chromium reduction using granular magnesium as reducing agent and to investigate the affects of various operationa...
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Chromium through natural processes and human activities enters the air, soil and water. Chromium-resistant bacteria are capable of reducing toxic Cr(VI) to less toxic Cr(III). In this work, batch studies were conducted to evaluate the effect of environmental factors on the rate of Cr(VI) reduction from synthetic wastewater of metal plating industry by Bacillus cereus under aerobic conditions. T...
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Cr stable isotope measurements can provide improved estimates of the extent of Cr(VI) reduction to less toxic Cr(III). The relationship between observed (53)Cr/(52)Cr ratio shifts and the extent of reduction can be calibrated by determining the isotopic fractionation factor for relevant reactions. Permeable reactive barriers (PRB) made of Fe(0) and in situ redox manipulation (ISRM) zones effect...
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Background: Cr (VI) is a highly toxic and carcinogenic contaminant and that are used in the steel industry and other chemical industries such as the leather industry, pigment production, electroplating of metals and the production of anticorrosive compounds. Its waste enters the environment and subsequently enters the water and food sources. Therefore, in order to protect the environment as wel...
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